Cash payment to transporter

In case of transport agency if PAn number is provided than TDS not required to deduct otherwise 20% to be deductde.

yes you can do.PAN  Number  to be considerd .

What will be the treatment on this below transporter's payment

" If one individual person got transferred by his company from one place to another place , where had to avail transportation facility to carry his household items. and finally bill was raised by carrying agency of65000/- for this. 

My quetion is 

1. Can that person pay by Cash of total Amt like65000/- in a single payment

2. If not above, then how will he pay that ? in line who will be liable for what ( Is that person or transport agency are bind to any provison) ?

3. If that person will take reimbursement of that total amount from his company , then,  is there any obligation to any law will be applicable to comapny's taxation or payment procedures ?

it will be appreciated if you guys encounter the questions one by one to draw more discussion or solution... thanks